Traditionally phenol and formaldehyde containing adhesives are used in wood products such as plywood, laminated veneer lumber, particle wood panels and laminates. There is a strong legal drive from sanitary authorities in Canada the US and the EU towards more stringent limitations up to a complete ban of phenol formaldehyde (PF) adhesives in wood panels.
The reasons is that they are actually releasing formol for years after manufacturing. Another important driver is the Act on Public Procurement enacted at the beginning of the year 2017 which highlights these public health and environmental considerations. This, in turn, drives wood product manufacturers to find bio-based and safe alternatives to these petroleum-based, toxic and expensive adhesive components.
VTT has developed CatLignin technology for producing reactive lignin from pulp industry side streams currently used for energy production. Due to its superior reactivity, CatLignin is an ideal replacement for phenol in phenol formaldehyde resins and could become a new, high-value product for pulp mills. In addition, the CO2 footprint of lignin is only approximately 20% of the footprint of phenol.
Resins have a significant impact on CO2 footprint of engineered wood products. For example in plywood, around half of CO2 footprint is caused by resin usage. Replacing phenol with lignin also reduces formaldehyde usage. To put this in context there are currently six million tons of phenol formaldehyde resins produced annually.
Senior VTT Scientist Hanne Wikberg says: “The suitability of lignin for a variety of applications has been investigated for decades, but only now we have found a way to use it as a phenol substitute in significant quantities in resins. VTT’s CatLignin technology represents a technological leap, offering new business opportunities to many industrial players”
This new material brings new business opportunities for the entire value chain, from lignin producers to adhesive and wood product manufacturers and end-users. In practice, this means pulp mills, adhesive, wood product and laminate manufacturers and their customers, such as kitchen cabinet and furniture brands.
The reactive lignin manufacturing technology can be integrated into pulp mills. Unlike existing technologies, the virtue of this process is the possibility to modify the lignin structure already at the pulp mill. Lignin structure can be tailored and therefore optimized specifically for each application.
Potential of CatLignin
- The CatLignin material has potential as a substitute for a wide range of fossil-based chemicals in adhesive, rubber and plastic applications. Its anti-oxidative properties are expected to improve weather resistance reducing the need for fossil-based and expensive additives used today.
- The CatLignin technology won the resource scarcity category in the New Tree 2017 competition in Finland on 1st February 2017 jointly with another VTT technology LigniOx concrete plasticizer solution. The competition jury – which consisted of experts from environmental and forestry sector together with societal and economic experts as well as Members of the Parliament of Finland – were particularly impressed by the societal importance and economic potential of the technology.
The Catlignin technology development is underway in a project funded by Tekes, the Finnish Funding Agency for Innovation, and VTT. This technology has already attracted a great deal of interest throughout the whole value chain and VTT is currently seeking partners for upscaling and commercialization of the technology.
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