1. Biodegradation is a process, not an end result.
Biodegrade showing tractor at biodegradable compost heap Biodegradation occurs when materials are broken down into simpler materials by bacteria, fungi, or other biological means. The end result you are looking for is probably home or industrial compostability, which is where biodegradation can lead. Ditto for marine biodegradation.
From a waste reduction perspective, the term does not guarantee anything of specific benefit. In fact, making promotional claims specifically related to biodegradability can get you in a great deal of trouble. You may be surprised to learn that it is illegal in the state of California to make claims related specifically to biodegradability. A number of well-known consumer-facing companies have been successfully sued by the folks in Sacramento after making a generic biodegradability claim.
The best way to make a claim is to have a specific package tested and/or certified for compostability or marine biodegradability. This can take 18-24 months, given the series of tests and approvals that must occur.
2. Disintegration and fragmentation are not biodegradation.
But, they can lead to it. This is the case with polylactic acid (PLA), which must disintegrate into small pieces before microbes begin the degradation process. Keep in mind that disintegration and fragmentation that don’t lead to full biodegradation can also lead to microplastics, which may be a worse situation than the problem they were trying to solve.
3. The certification process is complex, timing consuming, and costly.
All roads lead to meeting the standard established by ASTM-D6400. For example, the industrial compostability test for a plastic film starts with the ASTM-D5388 methodology to measure the carbon elements that are converted into gas as a measure of how much of the film biodegrades and over what time period. USDA biodegradable certificate
The film will also need to be tested against ISO 16929, the standard for disintegration. For reference, disintegration is successful when less than 10% of the starting reference material is captured on a screen 2mm x 2mm in size.
The sample must also be tested for heavy metal content and toxicity to determine the percentage of seeds that germinate in the soil after a plastic product is biodegraded into compost.
All of the test results are then measured against ASTM-D6400 requirements as follows:
- Results of biodegradation in industrial compost conditions as tested by ASTM-D5338 protocols must indicate 90% biodegradation within 180 days.
- Disintegration according to ISO 16929 must reach 90% within 12 weeks.
- Heavy metal content and toxicity levels must be below ASTM-D6400 limits.
- If your film passes all of these tests, in can be certified as industrial compostable. (Note that no accepted methodology exists for marine biodegradability certification, as the ASTM standard has lapsed.)
4. Generally speaking, certification for compostability requires that the entire structure and/or all of its components be tested and certified.
Let’s say that you want to package your frozen french fries in a more sustainable bag, say 1.0 mil thick. You find an extruder claiming that their film has been certified as industrial compostable by either of the two primary certification agencies – Biodegradable Products Insitute (BPI) here in the U.S., or TUV in Europe. Great! Are you done? Nope.
First, you need to determine what gauge of film was tested and certified. If the film was 1.2 mil and you want 1.0 mil film, you’ve passed first grade. If you want 1.5 mil film, you’ll need to start testing from scratch, using 1.5 mil film (or thicker).
If you’re not printing anything on the bag, coloring or tinting it, you’re probably done. However, if you want a nice white bag with 6 color printing, you’ll need to ensure that all of the colorants and inks are BPI or TUV approved for industrial compostability. If not, you will need to either find approved colorants, or have the finished bag sent through the entire testing and certification process again!
5. Biodegradation is not a panacea
Partially biodegraded materials are still pollutants. Further, the results of biodegradation are water vapor and greenhouse gases such as carbon dioxide, methane, and ammonia. So, if climate change is the number one problem, and greenhouse gas emissions are the primary culprit, you have to wonder if the cure isn’t worse than the disease.
6. Biodegradation is the last line of defense
It will almost always be preferable to reduce, reuse and recycle packaging than to have it biodegrade. The first three strategies keep the molecule in play, so to speak. Biodegradation removes the carbon-hydrogen bond in materials, which also eliminates both their performance features and energy value still present in the first three strategies. Thus, the real value of biodegradation is a safeguard against environmental impact, should packaging “leak out” of a closed loop system.TVA biodegrade biodegradable certification
7. Does this mean that it’s not reasonable to consider biodegradable packaging (i.e., home or industrial compostable) over recycling?
In general, the value of recycling is that it keeps the hydrocarbon molecule (for plant-based resins the carbohydrate molecule) in play, so to speak. The value of the molecule is based on the bonds between hydrogen and carbon, which contain both the inherent performance advantages of plastics and provide the energy potential used for fuel. Once that bond is broken and the carbon is released into the atmosphere, it is no longer sequestered and thus not available for additional use.
TVA biodegrade biodegradable certification marineOnly a well-conceived Life Cycle Analysis can determine whether or not composting is better than recycling. That LCA needs to examine the environmental and economic costs of the recycling process, specifically related to transportation and reprocessing.
Also, we think of landfills as villains. In reality, it might be better to develop a system whereby the truly recyclable materials are skimmed off the top, the food waste is composted, and the materials left are used to produce energy or—heaven forbid!—sequestered in a landfill for later use. In this scenario, a landfill would more aptly be known as an underground carbon sink!
8. ASTM, ISO, and similar standards were written to accommodate PLA many years ago and may no longer reflect the state of the art.
As mentioned earlier, current plastics biodegradation certification standards require disintegration. Biodegradable Pull Quote Bob LHowever, there are newer materials on the horizon that can biodegrade without the need for disintegration, which should lead to a significant reduction in the creation of microplastics.
Ironically, this environmental benefit does not allow these materials to be certified for compostability or marine biodegradation. Thus, standards need to be revised or rewritten to reflect the value and contribution of these materials.
- What are Bioplastics and Biopolymers?
- Bioplastics Brands
- Bioplastics Awards
- What is the Difference Between Biodegradable, Compostable and OXO Degradable?
- The History and Most Important Innovations of Bioplastics
- What are Drop-In Bioplastics?
- History of Cellophane
- The History of Elephant Grass Bioplastics
- Bioplastics Companies
- Top Bioplastics Producers
- Polylactic acid or polylactide (PLA)
- What is Bio-BDO?
- McDonalds and the Polystyrene Connections
- The Future of Polystyrene
- Bioplastic Feedstock 1st, 2nd and 3rd Generations
- Palm Oil and The Bioplastics Industry
This article was published on plasticstoday.com and written by Robert Lilienfeld